کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5407657 | 1393225 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Indirect detection of NMR via geometry-dependent dipolar fields, revisited
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
We explore the dipolar interactions between two separate nuclear spin ensembles in a mixture containing oil and water. Here we expand initial results [C.A. Meriles, W. Dong, J. Magn. Reson. 181 (2006) 331.] to the case in which both systems have the shape of flat, stacked disks. We find that-in spite of the strong inhomogeneity of the coupling dipolar field-the signal encoded in one of the components can be made approximately proportional to the magnetization in the other. This allows us to use one of these systems as a 'sensor' to indirectly reconstruct the resonance spectrum or to determine the relaxation time of the 'sample' system. In the regime in which dipolar interactions are sufficiently strong, our method can be set to scale-up weaker signals in a non-linear fashion, which, potentially, could allow one to introduce contrast or to improve detection sensitivity of less magnetized samples.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetic Resonance - Volume 186, Issue 2, June 2007, Pages 330-336
Journal: Journal of Magnetic Resonance - Volume 186, Issue 2, June 2007, Pages 330-336
نویسندگان
Wei Dong, C.A. Meriles,