کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
54224 47001 2015 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Kaolinite-titanium oxide nanocomposites prepared via sol-gel as heterogeneous photocatalysts for dyes degradation
ترجمه فارسی عنوان
نانوکامپوزیت های کائولنیت تیتانیوم اکسید تهیه شده از طریق سل ژل به عنوان فتکاتالیست های ناهمگن برای تخریب رنگ ها
کلمات کلیدی
کائولینیت، دی اکسید تیتانیوم، عکسبرداری، متیلن آبی، متیل نارنجی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی


• Kaolinite-titanium oxide nanocomposites were prepared via sol-gel.
• Kaolinite-titanium oxide catalysts were studied in dyes photodegradation.
• Catalytic photodegradation of methylene blue and methyl orange II were investigated.

A purified natural kaolinite was functionalized with titanium(IV) isopropoxide via the hydrolytic sol-gel route and thermally treated at several temperatures, between 100 and 1000 °C, for 24 h. The resulting solids were used for photodegradation (λ=365 nm, 30 W) of Methylene Blue (MB) and Methyl Orange II (MOII) dyes. All the solids efficiently degraded the dyes and almost total bleaching of the aqueous solutions was observed after 1 h. The best results were found for the solid heated at 400 °C, which degraded 93% of MOII and 99% of MB. Comparative studies with titanium oxide P25 from Degussa were tested and the results reveal lower yields than our systems (45% MB and 15% MOII, 1 h). Kaolinite could promote the dispersion of TiO2 on the clay surface allowing a fast degradation of dyes. This effect was confirmed by comparison of the results from isolated components (titanium oxide and kaolinite) and titanium oxide-kaolinite nanocomposites.

Figure optionsDownload high-quality image (109 K)Download as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 246, 15 May 2015, Pages 133–142
نویسندگان
, , , , , , , , , , ,