Site-specific ion desorption from condensed F3SiCD2CH2Si(CH3)3 induced by Si-2p core-level ionizations studied with photoelectron photoion coincidence (PEPICO) spectroscopy, Auger photoelectron coincidence spectroscopy (APECS) and Auger electron photoion

► Ion desorption from condensed F3SiCD2CH2Si(CH3)3 by Si-2p ionization was studied. ► PEPICO, APECS and AEPICO spectroscopies were used. ► Site-specific F+ desorption and non-site-specific H+ desorption were observed.