Structural and electronic properties of hexa-adamantyl-hexa-phenylbenzene molecules studied by low temperature scanning tunneling microscopy

► Observation of Hexa-Adamantyl-Hexa-PhenylBenzene Molecules deposited on Ag(111) surfaces at ambient and low temperature. ► STM observations of two different networks after room temperature deposition. ► STM observations of an unexpected contrast on each molecule as a function of bias voltage. ► Low temperature observation of single molecules exhibiting the same contrast. ► ASED-MO and ESQC-STM image calculations.