کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5424829 | 1395838 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Eu valence in ultra-thin layers of EuF3 derived from photon energy dependent photoemission and photoabsorption
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Eu valence in ultra-thin layers of EuF3 derived from photon energy dependent photoemission and photoabsorption Eu valence in ultra-thin layers of EuF3 derived from photon energy dependent photoemission and photoabsorption](/preview/png/5424829.png)
چکیده انگلیسی
X-ray absorption (XAS) and resonant photoemission (RESPE) have been used to study Eu valence in ultra-thin EuF3 layers grown by MBE. It was shown that resonant photoemission (RESPE) from EuF3 ultra-thin layers exhibits different features for photon energies close to the 4d-4f threshold (130-150Â eV) and the 3d-4f excitation region (1120-1170Â eV). For the low energy resonance a clear effect of resonance induced Eu2+ states (final state 4f6) has been found whereas no divalent Eu states have been observed when photon energy was tuned to the 3d-4f transition. Our results indicate that Eu valence derived from the XAS and RESPE spectra depends on photon energy and is dominated by the final state effects for the 4d-4f resonance. An explanation is given based on the screening effect and different decay channels of the 4d-4f and 3d-4f resonances.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Surface Science - Volume 602, Issue 8, 15 April 2008, Pages 1525-1531
Journal: Surface Science - Volume 602, Issue 8, 15 April 2008, Pages 1525-1531
نویسندگان
J. Szade, W. Burian, M. Zangrando, F. Bondino, E. Magnano, S. Widuch, Z. CeliÅski,