کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5425344 | 1395854 | 2008 | 8 صفحه PDF | دانلود رایگان |
Metal nanowires (Nb, V, Pd and Fe) were studied by atomic force microscopy (AFM). The wires were produced by metal deposition onto faceted sapphire substrates. Periodic arrangements of wires of about 7Â ÃÂ 10â8Â m width and 3Â ÃÂ 10â8Â m height, accompanied with a wire length of about 1Â ÃÂ 10â3Â m were analysed. The grain size was normally about 2Â ÃÂ 10â8Â m.Prolonged scanning in contact mode leads to massive material agglomeration on the back of the substrate facet. Short-run measurements successfully image the wire morphology but impede an exact determination of the phase transition pressures.At 10â2Â Pa hydrogen gas pressure, the formation of a hydride along the wire axis of Nb-wires was verified in short-run experiments by AFM images including contour-lines as well as height histograms. The lattice of a 30Â nm thin Nb-wire locally expands upon hydride formation with about 2Â nm in vertical direction. This result agrees with the predictions of a model assuming linear elasticity, an ideally rigid substrate, and infinitely strong adhesion of the nanowires. No lateral expansion was detectable.
Journal: Surface Science - Volume 602, Issue 1, 1 January 2008, Pages 54-61