کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5427854 1508648 2015 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
High-resolution absorption measurements of NH3 at high temperatures: 500-2100 cm−1
موضوعات مرتبط
مهندسی و علوم پایه شیمی طیف سنجی
پیش نمایش صفحه اول مقاله
High-resolution absorption measurements of NH3 at high temperatures: 500-2100 cm−1
چکیده انگلیسی


- Absorption spectrum of ammonia recorded at 1300 K.
- 2000 line assignments, 851 newly assigned.
- Several bands observed for the first time.

High-resolution absorption spectra of NH3 in the region 500-2100 cm−1 at temperatures up to 1027 °C and approximately atmospheric pressure (1013±20 mbar) are measured. NH3 concentrations of 1000 ppm, 0.5% and 1% in volume fraction were used in the measurements. Spectra are recorded in high temperature gas flow cells using a Fourier Transform Infrared (FTIR) spectrometer at a nominal resolution of 0.09 cm−1. Measurements at 22.7 °C are compared to high-resolution cross sections available from the Pacific Northwest National Laboratory (PNNL). The higher temperature spectra are analysed by comparison to a variational line list, BYTe, and experimental energy levels determined using the MARVEL procedure. Approximately 2000 lines have been assigned, of which 851 are newly assigned to mainly hot bands involving vibrational states as high as v2=5.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 167, December 2015, Pages 126-134
نویسندگان
, , , , ,