کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5431174 | 1397440 | 2006 | 18 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Line intensities of acetylene in the 3-μm region: New measurements of weak hot bands and global fitting
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
طیف سنجی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
About 170 line intensities of 14 weak parallel hot bands of acetylene have been measured in the 3-μm region. Absolute values of line intensities are obtained with a mean uncertainty of 10%, except for a few lines of 3 very weak bands (uncertainty up to 20%). Vibrational transition dipole moment and Herman-Wallis coefficients have been determined for each measured band. These measured line intensities together with previously published ones (JQSRT 2005;92:239-60) have been treated simultaneously within the framework of the effective operators approach. Using only 6 effective dipole moment parameters, it was possible to reproduce the 591 measured line intensities of the 20 bands with a root mean square of the residuals equal to 4.2%.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 97, Issue 1, January 2006, Pages 81-98
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 97, Issue 1, January 2006, Pages 81-98
نویسندگان
O.M. Lyulin, V.I. Perevalov, J.-Y. Mandin, V. Dana, D. Jacquemart, L. Régalia-Jarlot, A. Barbe,