کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5435482 | 1509352 | 2017 | 9 صفحه PDF | دانلود رایگان |
- The shaddock peels are used as precursor for N-doping porous carbon.
- The BC substrate permits large loading mass and remarkable tensile property.
- The paper electrode exhibits excellent areal capacitance of 2004Â mFÂ cmâ2.
- The synthesis method is simple and cost-effective.
A flexible N-doped activated shaddock peel carbon (N-ASPC)/graphene (GN)/bacterial cellulose (BC) hybrid paper electrode with remarkable mechanical properties and large mass loading (8 mg cmâ2) is fabricated. This flexible electrode integrates extraordinary special capacitance N-ASPC from resource-rich fruit waste (shaddock peel), highly conductive GN and ultrafine three-dimensional (3D) fibrous network structure BC, which exhibits remarkable areal capacitance of 2004 mF cmâ2 (250.5 F gâ1), excellent rate performance with 82.3% retention from 2 to 40 mA cmâ2, good cyclic stability with 97% retention over 10,000 cycles, ultrahigh tensile strength (32 MPa) and good conductivity (1550 S mâ1). The symmetric supercapacitor based on two identical N-ASPC/GN/BC film electrodes with an operation voltage of 1.4 V in Na2SO4 electrolyte can deliver a maximum energy density of 0.158 mW h cmâ2 and a maximum power density of 28 mW cmâ2. Therefore, the binder-free N-ASPC/GN/BC electrodes hold great promise for flexible energy-storage devices.
(a) Optical image of a free-standing N-ASPC/GN/BC paper. (b) Stress-strain curves of N-ASPC/GN/BC paper. (c) Specific capacitance at different current densities.97
Journal: Synthetic Metals - Volume 226, April 2017, Pages 104-112