کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5441077 | 1510376 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Multinuclear NMR investigation of temperature effects on structural reactions involving non-bridging oxygens in multicomponent oxide glasses
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
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چکیده انگلیسی
The energetics of structural mechanisms involving inter-conversions among oxygen species dictate structure and properties of oxide glasses. We explored the change in boron coordination as a function of fictive temperature in glasses containing Zr and/or Na. There was lower boron coordination in the Zr-containing glass, and there was less decrease in boron coordination with temperature. We relate this difference to changes in the energetics of Zr-O-Si and Na-O-Si linkages. Furthermore, we varied fictive temperature to explore the distribution of non-bridging oxygens (NBO) on Al and Si in a Ca aluminosilicate and a Y aluminosilicate. As temperature increased, Al-NBO% increased. We attribute this change with temperature to differences in the energetics of Si-NBO and Al-NBO, which result in a strong preference for Si-NBO that is predicted to persist over a wide temperature range.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 471, 1 September 2017, Pages 179-186
Journal: Journal of Non-Crystalline Solids - Volume 471, 1 September 2017, Pages 179-186
نویسندگان
Elizabeth I. Morin, Jonathan F. Stebbins,