کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5441262 1510379 2017 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Mixed-modifier effect in (Ca,Mg) metaphosphate glasses
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Mixed-modifier effect in (Ca,Mg) metaphosphate glasses
چکیده انگلیسی
The effect of modifier mixing on structure and properties of (Ca, Mg) metaphosphate glasses is considered across the binary join of xMgO-(1-x)CaO-P2O5. Pronounced extrema in hardness, Young's modulus, local creep and glass transition temperature are related to variations in modifier precipitation. Both alkaline earth species compete for octahedral lattice sites, what leads to an increase in the fraction of [MgO4] tetrahedral units at equimolar mixing. At the same time, the structural backbone of phosphate Q2 species is affected through favorable formation of ring- and chain-like superstructures in the presence of Ca2 + and Mg2 +, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 468, 15 July 2017, Pages 74-81
نویسندگان
, , ,