کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
54494 | 47011 | 2015 | 11 صفحه PDF | دانلود رایگان |

• Flexible micromonoliths 70,000 m−1 as S/V ratio and 20 μm as characteristic length.
• PBI micromonolith-type stack as microstructured support.
• Pt nanoparticles supported on amino functionalized ETS10 crystals.
• Pt based catalytic films on PBI microchannels for n-hexane combustion.
• 75% hexane conversion at 225 °C with 5 ms as gas–solid contact time.
Flexible polybenzimidazole (PBI) micromonoliths prepared by microtransfer moulding are herein proposed for the first time as G-S contactors for catalytic applications. Macroporous polymeric supports with 20 μm as characteristic length and 70,000 m−1 as S/V ratio have been coated by covalent linkage with Pt supported on amino functionalized ETS-10 crystals. As a proof of concept, the catalytic performance of the Pt modified PBI micromonoliths has been successfully demonstrated for indoor quality control, i.e. n-hexane removal at ppm level.
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Journal: Catalysis Today - Volume 241, Part A, 1 March 2015, Pages 114–124