کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
55205 47043 2012 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Chemically modified expended starch grafted Ni-acetylacetonate/TBAB: An effective reusable catalytic combination for the cycloaddition of carbon dioxide to epoxides
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Chemically modified expended starch grafted Ni-acetylacetonate/TBAB: An effective reusable catalytic combination for the cycloaddition of carbon dioxide to epoxides
چکیده انگلیسی

Starch is renewable, biodegradable and relatively inexpensive material that has been used for the grafting of nickel(II) acetylacetonate by covalent linkage. The prepared material in combination with tetrabutyl ammonium bromide is found to be a very active, selective and recyclable catalytic system for the cycloaddition of CO2 and epoxides without co-solvent under relatively mild reaction conditions. Importantly, the starch grafted nickel catalyst and TBAB are easily recovered after the reaction and reused many times without any loss in catalytic activity.

Figure optionsDownload high-quality image (110 K)Download as PowerPoint slideHighlights
► Chemically modified expended starch grafted metal complex.
► Chemical fixation of carbon dioxide.
► Renewable feedstock as support.
► Facile recovery and recycling of the catalysts.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 198, Issue 1, 30 December 2012, Pages 204–208
نویسندگان
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