N2O decomposition over Fe-FER: A Mössbauer study of the active sites

Iron ferrierites with low iron content (Fe/Al between 0.018 and 0.072) were used as model catalysts to evaluate the participation of individual iron species, with special interest in the role of iron in β cationic sites, for formation of active sites for N2O decomposition. Despite low iron content, the catalysts with prevailing iron located in β sites of two types exhibited high conversions of N2O and activity increase with increase of iron loading. These results indicate formation of the active iron species already at very low concentrations, while at higher concentration level would part of the iron enter also into less active positions. Semi-quantitative analysis of the TOF values of individual iron centers was done using the recently established Mössbauer parameters of the Fe(II) parameters for individual iron cationic species, i.e. β (β-1 and β-2) and α sites [1]. The evaluation of the TOF presents a new support for the role of iron in β sites in N2O decomposition and further indicates similar role of both β-1 and β-2 sites in formation of the Fe⋯Fe active site.

Figure optionsDownload high-quality image (84 K)Download as PowerPoint slideHighlights
► Fe ferrierites (Fe/Al < 0.1) was studied as model catalysts for N2O decomposition.
► Catalysts with Fe prevailing located in β sites exhibited high N2O conversion.
► Mössbauer spectroscopy results confirmed total oxidation of Fe(II) in Fe-FER by N2O.
► The evaluation of the TOF evidenced the role of Fe in β sites in N2O decomposition.
► Both β-1 and β-2 sites participate in formation of the Fe…Fe active sites.