کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
55927 47066 2011 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
CH4 decomposition on Ni and Co thin layer catalysts to produce H2 for fuel cell
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
CH4 decomposition on Ni and Co thin layer catalysts to produce H2 for fuel cell
چکیده انگلیسی

Ni and Co supported on SiO2 and Al2O3 Silica Cloth Thin Layer Catalysts (TLC) were investigated in the Catalytic Decomposition of Natural Gas (CDNG) reaction using a Multilayer Catalytic Reactor (MCR). The influence of support and reaction temperature was evaluated with the aim to design a novel catalyst suitable to develop a dual-step process to produce pure hydrogen for fuel cell. Ni and Co silica supported catalyst, due to the low metal supported interaction (MSI) characterizing such systems, were not found suitable to efficiently perform CDNG reaction. On the contrary in case alumina was used as support both metals strongly interact with surface becoming so more resistant to sintering. In addition in case the metals (both Ni and Co) strongly interact with support surface, the formation of encapsulating carbon is depressed and only filamentous carbon forms. Using Ni and Co TLC supported on Al2O3 samples it has been possible to realize a cyclic dual-step process based on reaction and regeneration in oxygen stream without any catalyst detriment.A deactivation modelling to discriminate the role of sintering and coking on the deactivation pattern is proposed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 171, Issue 1, 10 August 2011, Pages 60–66
نویسندگان
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