کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
56239 47078 2010 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Total catalytic oxidation of a side-product for an autothermal restoring hydrogen process
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Total catalytic oxidation of a side-product for an autothermal restoring hydrogen process
چکیده انگلیسی

The catalytic total oxidation of toluene is used to bring the required calories to restore hydrogen from methylcyclohexane (MCH). Two coupled reactions, both catalyzed by Pt/alumina, are thus considered in one autothermal heat-exchanger reactor (HER): endothermic dehydrogenation of methylcyclohexane and catalytic combustion of less than 10% of produced toluene (6% for the chemical reaction, about 4% for heat losses). Both reactions are carried out at 350 °C. Methylcyclohexane and toluene light-off curves have been performed in one elementary module. Methylcyclohexane combustion has been eliminated due to its safety drawbacks, although the MCH combustion provides best stability to autothermal HER.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 157, Issues 1–4, 17 November 2010, Pages 321–326
نویسندگان
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