کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
56647 47090 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Mn/Mg/Al-spinels as catalysts for SOx abatement: Influence of CeO2 incorporation and catalytic stability
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Mn/Mg/Al-spinels as catalysts for SOx abatement: Influence of CeO2 incorporation and catalytic stability
چکیده انگلیسی

Mg,Mn,Al-oxides with spinel structure, Al/(M2+ + Al) molar ratio of 0.25 and 0.50 and an Mn/Mg molar ratio of 0.30 have been evaluated as catalysts for SOx removal under conditions similar to those found in FCC units. The best performance was that of the sample with the higher aluminium content. The incorporation of CeO2 in this sample favored SOx uptake for short reaction times as well as the reduction of the sulfated catalysts. When the regeneration was started at 530 °C, only H2S was observed as reaction product, but when this step started at 650 °C, the release of SO2 preceded that of H2S, regardless of the chemical composition of the sample. As to the additive performance for successive reaction–regeneration cycles, the incorporation of CeO2 produced a less efficient catalyst with regard to the removal of the SO2 along the process, but with a higher regeneration efficiency and a lower formation of SO2 as regeneration product.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 149, Issues 3–4, 30 January 2010, Pages 309–315
نویسندگان
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