کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
58846 47175 2006 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Addition of carbon dioxide to allyl glycidyl ether using ionic liquids catalysts
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Addition of carbon dioxide to allyl glycidyl ether using ionic liquids catalysts
چکیده انگلیسی

The addition of carbon dioxide to allyl glycidyl ether (AGE) was investigated without using any solvent in the presence of ionic liquid as catalyst. Ionic liquids based on 1-ethyl-3-methylimidazolium (EMIm), 1-butyl-3-methylimidazolium (BMIm), and 1-hexyl-3-methylimidazolium (HMIm) with different anions such as Cl−, BF4−, PF6− were used as catalysts. The reaction was performed in a 50 mL stainless steel autoclave. The conversion of allyl glycidyl ether was affected by the structure of imidazolium salt ionic liquids; the one with the cation of bulkier alkyl chain length and with more nucleophilic anion showed better reactivity. Reaction temperature and carbon dioxide pressure enhanced the addition of carbon dioxide to AGE.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 115, Issues 1–4, 30 June 2006, Pages 130–133
نویسندگان
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