کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
59165 | 1419451 | 2013 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Suzuki-Miyaura cross-coupling reaction catalyzed by a highly stable Pd(P-Phos)Cl2 complex at room temperature under air
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new Pd(P-Phos)Cl2 complex was synthesized and characterized by 1H NMR, 13C NMR, 31P NMR, and X-ray single crystal structure determination. The complex proved to be a highly stable and efficient catalyst for substrates with a wide range of functional groups in Suzuki-Miyaura cross-coupling reactions under air at room temperature. Low catalyst loadings were employed and turnover number of up to 49000 was obtained.
Graphical AbstractA new Pd(P-Phos)Cl2 complex has been synthesized and characterized. The complex catalyzed the Suzuki-Miyaura cross-coupling reactions of various aryl halide and arylboronic acids in medium to excellent yields under air at room temperature.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Catalysis - Volume 34, Issue 9, September 2013, Pages 1667–1673
Journal: Chinese Journal of Catalysis - Volume 34, Issue 9, September 2013, Pages 1667–1673
نویسندگان
Yicen Ge, Yujing Cheng, Haiyan Fu, Xueli Zheng, Ruixiang Li, Hua Chen, Xianjun Li,