کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
59910 | 1419449 | 2013 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: One-pot synthesis of primary amides on bifunctional Rh(OH)x/TS-1@KCC-1 catalysts One-pot synthesis of primary amides on bifunctional Rh(OH)x/TS-1@KCC-1 catalysts](/preview/png/59910.png)
A new microporous/mesoporous composite with a core-shell structure, TS-1@KCC-1, was fabricated in a microemulsion system by coating flower-like mesoporous silica (KCC-1) on the crystal surface of TS-1 zeolite. The synthesis conditions and a possible formation mechanism were studied in detail for the TS-1@KCC-1 material. A suitable temperature and assembly time were found to be 373–393 K and 4 h, respectively. The shell thickness of TS-1@KCC-1 was conveniently tuned in the range 25–80 nm. Rh(OH)x species were supported on TS-1@KCC-1, giving rise to a novel bifunctional tandem catalyst Rh(OH)x/TS-1@KCC-1, which effectively catalyzed the one-pot synthesis of primary amides directly from aldehydes, ammonia, and hydrogen peroxide.
A novel bifunctional tandem catalyst for the one-pot synthesis of primary amides directly from aldehydes, ammonia, and hydrogen peroxide was synthesized.Figure optionsDownload as PowerPoint slide
Journal: Chinese Journal of Catalysis - Volume 34, Issue 11, November 2013, Pages 2057–2065