کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
60016 1419437 2014 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation and catalytic performance of perfluorosulfonic acid-functionalized carbon nanotubes
ترجمه فارسی عنوان
تهیه و عملکرد کاتالیزوری نانولوله های کربنی پرتویورسولفونیک اسید کارکرد یافته
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی

Perfluorosulfonic acid-functionalized carbon nanotubes were prepared by liquid deposition of the perfluorosulfonic acid-polytetrafluoroethylene copolymer and characterized by N2 adsorption, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, and acid-base titration. The effects of reaction temperature and the type of solvent were investigated. The results showed that these solid acids are very stable in both polar and non-polar solvents and can maintain their acidity up to 300 °C. Higher activity and better stability were observed over these materials in the alkylation of hydroquinone compared with poly(styrene sulfonic acid)-grafted carbon nanotubes.

Graphical AbstractPerfluorosulfonic acid-functionalized carbon nanotubes were prepared and exhibit higher activity and better stability in the alkylation of hydroquinone than poly(styrene sulfonic acid)-functionalized carbon nanotubes.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Catalysis - Volume 35, Issue 11, November 2014, Pages 1874–1882
نویسندگان
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