Catalytic Oxidation of Aryl Alkyl Sulfides Using Immobilized Vanadyl Ions within Nanoreactors of Al-MCM-41

VOSO4 immobilized within nanoreactors of Al-MCM-41 (VO2+/Al-MCM-41) was synthesized and characterized by X-ray diffraction, Fourier transform infrared spectroscopy, nitrogen adsorption-desorption, and chemical analysis techniques. The prepared VO2+/Al-MCM-41 successfully catalyzes the oxidation of aryl alkyl sulfides and up to 99% conversion and 90% selectivity for the corresponding sulfoxides were obtained with H2O2 as oxidant in acetonitrile at room temperature in 30 min.

The facile catalytic oxidation of aryl alkyl sulfides with up to 99% conversion and 90% selectivity to the corresponding sulfoxides using H2O2 in acetonitrile at room temperature in 30 min with VOSO4 immobilized within nanoreactors of Al-MCM-41 is reported.Figure optionsDownload as PowerPoint slide