کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
60603 47538 2016 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Titration and quantification of open and closed Lewis acid sites in Sn-Beta zeolites that catalyze glucose isomerization
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Titration and quantification of open and closed Lewis acid sites in Sn-Beta zeolites that catalyze glucose isomerization
چکیده انگلیسی


• IR molar extinction coefficients measured for pyridine and CD3CN bound to Sn sites.
• Equimolar binding of NH3, n-propylamine, pyridine, CD3CN to Lewis acidic Sn sites.
• Pre-poisoning of Sn-Beta suggests open Sn sites catalyze glucose isomerization.
• Open Sn sites counted by CD3CN can normalize initial glucose isomerization rates.
• Isomerization rate constants are 50× higher on hydrophobic than on hydrophilic Sn-Beta.

Methods to quantify framework Lewis acidic Sn4+ sites in zeolite Beta (Sn-Beta) with four Lewis base titrants (pyridine, deuterated acetonitrile, n-propylamine, ammonia) were developed using infrared (IR) spectroscopy or temperature programmed desorption (TPD). Integrated molar extinction coefficients (E, cm μmol−1) were measured for IR bands of pyridine adsorbed to Lewis acidic Sn sites (E(1450 cm−1) = 1.42 ± 0.30) and of CD3CN adsorbed to open (E(2316 cm−1) = 1.04 ± 0.22) and closed (E(2308 cm−1) = 2.04 ± 0.43) Sn sites, and differ from analogous E values for Lewis acidic Al sites by up to 3.6×. TPD of Sn-Beta samples after saturation with NH3 or n-propylamine (NPA) and purging to remove physisorbed species also enabled quantification of Lewis acid sites, which is seldom performed despite analogous methods that use such titrants to quantify Brønsted sites in solid acids. These four Lewis bases titrated Lewis acidic Sn sites with equimolar stoichiometry and counted similar numbers of Sn sites on low-defect Sn-Beta samples synthesized in fluoride media (Sn-Beta-F) with high Sn content (Si/Sn <150). NPA binding on residual silanol defect sites, however, caused overestimation of Sn sites by TPD on Sn-Beta-F samples with low Sn content (Si/Sn >175) or high defect Sn-Beta samples prepared via post-synthetic insertion of Sn atoms into framework vacancy defects of dealuminated Beta zeolites (Sn-Beta-OH). Molar ratios of open-to-closed Sn sites varied widely (0.29–1.64) among the eight Sn-Beta samples studied here. Open Sn sites have been proposed as the dominant active sites for aqueous-phase glucose–fructose isomerization via intramolecular 1,2-hydride shift, consistent with successive poisoning of Sn-Beta samples with pyridine prior to measurement of initial glucose isomerization rates that suppressed reactivity at pyridine uptakes similar to the number of open Sn sites counted ex-situ by CD3CN. Measured first-order glucose isomerization rate constants in water (per open Sn, 373 K), which reflect free energy differences between isomerization transition states and two coordinated water molecules at Sn sites, were ∼50× higher on hydrophobic Sn-Beta-F than on hydrophilic Sn-Beta-OH zeolites. The characterization methods reported herein enable normalization of initial glucose isomerization turnover rates on Sn-Beta zeolites by their number of open Sn sites, as required prior to interpreting the catalytic consequences of structural heterogeneities introduced by differences in sample preparation or treatment history.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 335, March 2016, Pages 141–154
نویسندگان
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