کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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606301 | 1454525 | 2016 | 8 صفحه PDF | دانلود رایگان |
In this report, a novel molecular imprinted voltammetric sensor based on glassy carbon electrode (GCE) modified with platinum nanoparticles (PtNPs) involved in a polyoxometalate (H3PW12O40, POM) functionalized multi-walled carbon nanotubes (MWCNs) sheets was prepared for the determination of simazine (SIM). The developed surfaces were characterized by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) method. SIM imprinted GCE was prepared via electropolymerization process of 100 mM pyrrole as monomer in the presence of 0.1 M acetate buffer (pH 4.0) containing 25 mM SIM. The linearity range and the detection limit of the developed method were calculated as 1.0 × 10−10–5.0 × 10−9 M and 2.0 × 10−11 M, respectively. In addition, the voltammetric sensor was applied to wastewater samples. The stability and reproducibility of the voltammetric sensor were also reported.
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Journal: Journal of Colloid and Interface Science - Volume 470, 15 May 2016, Pages 14–21