کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
606451 1454531 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
High efficient removal of fluoride from aqueous solution by a novel hydroxyl aluminum oxalate adsorbent
ترجمه فارسی عنوان
حذف فلوراید از محلول های آبی با استفاده از جاذب جدید هیدروکسی آلومینیوم اگزالات
کلمات کلیدی
هیدروکسی آلومینیوم اکسالات، فلوراید، جذب، سینتیک، ترمودینامیک
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
چکیده انگلیسی

A novel adsorbent, hydroxyl aluminum oxalate (HAO), for the high efficient removal of fluoride from aqueous solution was successfully synthesized. The adsorbent was characterized and its performance in fluoride (F−) removal was evaluated for the first time. Kinetic data reveal that the F− adsorption is rapid in the beginning followed by a slower adsorption process; 75.9% adsorption can be achieved within 1 min and only 16% additional removal occurred in the following 239 min. The F− adsorption kinetics was well described by the pseudo second-order kinetic model. The calculated adsorption capacity of this adsorbent for F− by Langmuir model was 400 mg g−1 at pH 6.5, which is one of the highest capabilities of today’s materials. The thermodynamic parameters calculated from the temperature-dependent isotherms indicate that the adsorption reaction of F− on the HAO is a spontaneous process. The FT-IR spectra of HAO before and after adsorbing F− show adsorption mechanism should be hydroxyl and oxalate interchange with F−.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 464, 15 February 2016, Pages 238–245
نویسندگان
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