کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
607641 1454590 2013 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermosensitive hybrid hydrogels with silica nanoparticle-cross-linked polymer networks
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
Thermosensitive hybrid hydrogels with silica nanoparticle-cross-linked polymer networks
چکیده انگلیسی


• Novel thermosensitive hybrid hydrogels cross-linked by nanoparticles are prepared.
• Hydrogels can be facilely obtained by mixing reactive copolymer and nanoparticles.
• This method provides easy tunability of hydrogel properties.
• Swelling ratios are higher as compare to the conventional PNIPAM hydrogels.
• LCST of hybrid hydrogels is independent of the nanoparticles concentrations.

A simple methodology for the preparation of thermosensitive organic–inorganic hybrid hydrogels using silica nanoparticle-mediated polymer networks is described. A thermosensitive copolymer poly[N-isopropylacrylamide-co-(3-methacryloxypropyltrimethoxysilane)], (pNS), with reactive side chains (SiOCH3) was first synthesized by free radical polymerization using N-isopropylacrylamide (NIPAAm) and 3-methacryloxypropyltrimethoxysilane (MAPTS). Then, simple mixing of the aqueous solution of this copolymer with silica nanoparticle (SiP) suspensions at room temperature led to the formation of thermosensitive hybrid hydrogels cross-linked with silica nanoparticles (SiP) which did not require any other processing like washing for the removal of unreacted monomers and initiators. The effects of SiP content on gelation abilities, temperature-responsive behaviors, swelling and deswelling kinetics, and mechanical properties of the hydrogels were investigated. The results showed that transparent hybrid hydrogels with adjustable network structures were obtained within a few minutes to a couple of hours depending on the concentration of the copolymers and the silica nanoparticles. The hybrid hydrogels exhibited a lower critical solution temperature (LCST) of around 33 °C with no significant deviation from conventional poly(N-isopropylacrylamide) hydrogels; the LCST was not significantly affected by the concentration of silica nanoparticles (which in these systems serve as the cross-linkers). In addition, the hydrogels showed significantly large equilibrium swelling ratios, improved mechanical strength, and suitable deswelling behavior, which can easily be tuned by varying the composition of the hybrid hydrogels.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 405, 1 September 2013, Pages 109–117
نویسندگان
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