Highly efficient olefin oxidation catalysts based on regular nano-particles of titanium-containing mesoporous molecular sieves

Ti-MCM-41 and Ti-MCM-48 are successfully prepared by one step synthesis and post-synthesis at room temperature. The samples have been characterized by X-ray diffraction, SEM, TEM, nitrogen adsorption/desorption isotherms and UV–Vis spectroscopy. The results demonstrate the existence of an ordered mesoporous structure. The Ti species are grafted into the pure silica sieve frameworks without any evidence of the formation of non-skeleton anatase. The post-synthesis Ti-MCM-41 regular nano-particles display a higher conversion and selectivity as compared to that for both the post-synthesis Ti-MCM-48 and Ti-MCM-41 with ordinary particles, in the epoxidation of cis-cyclooctene with aqueous H2O2 as an oxidant. The enhanced catalytic activity may be attributed to the existence of a higher number of isolated tetracoordinated Ti active sites and regular nano-particles, which are conducive to the affinity of the reactants with active sites.

The post-synthesis Ti-MCM-41 possesses more isolated tetracoordinated Ti active centers and displayed a highly ordered structure, which facilitates high activity for the epoxidation of cis-cyclooctene with H2O2.Figure optionsDownload high-quality image (126 K)Download as PowerPoint slideResearch highlights
► The post-synthesis Ti-MCM-41 was synthesized by room temperature grafting methods.
► The post-synthesis Ti-MCM-41 has more isolated tetracoordinated Ti active centers.
► The post-synthesis Ti-MCM-41 displays high activity.