Adsorption of poly(ethylene oxide) on smectite: Effect of layer charge

The adsorption of polymers on clay is important in many applications. However the mechanisms of poly(ethylene oxide) (PEO) adsorption on smectite is not well elucidated at present. The aim of this study was to investigate the effect of layer charge density on the adsorption of PEO by smectite. The results indicated that both the hydrophobic interaction (between CH2CH2 groups and siloxane surface) and the hydrogen bonding (between ether oxygen of PEO and structure OH of smectite) lead to PEO preferential adsorption on the surface of low-charge smectite. In addition, the delamination of low-charge smectite in water is enhanced upon PEO adsorption presumably due to the hydrophilic ether oxygen of adsorbed PEO.

The hydrophobic interaction (between CH2CH2 groups and siloxane surface) and the hydrogen bonding (between structure OH and PEO's ether oxygen) are responsible for PEO adsorption on smectite.Figure optionsDownload as PowerPoint slide