Fabrication of silica nanotubes using silica coated multi-walled carbon nanotubes as the template

Silica nanotubes were synthesized using the multi-walled carbon nanotubes (MWCNTs) as the template material. First, we prepared silica coated MWCNT composites by surface oxidation of MWCNTs using KMnO4 in the presence of a phase transfer catalyst and followed by grafting of 2-aminoethyl 3-aminopropyl trimethoxy silane, AEAPS. The amine groups in grafted AEAPS on MWCNTs could activate the silica shell formation by acid–base interaction. The synthesized silica was formed a uniform layer on MWCNTs with a controllable thickness and possessed sturdy 3-dimensional stability. After calcinations at 800 °C, the inner MWCNTs of the composite were completely decomposed and the outer silica shell layer maintained without distortion of its original shape. Finally, we could obtain the silica nanotubes having 13.0 nm of average layer thickness.

Synthesized silica nanotubes by three step reactions: oxidation of MWCNTs, grafting with a silane coupling agent, and silica coating by TEOS.Figure optionsDownload as PowerPoint slide