کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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613594 | 880724 | 2006 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Electroosmotically enhanced mass transfer through polyacrylamide gels Electroosmotically enhanced mass transfer through polyacrylamide gels](/preview/png/613594.png)
We present an internal pumping strategy to enhance solute fluxes in polymer gels. The method is based on electroosmotic flow driven by an electric field applied across a gel that has been doped with charged colloidal inclusions. This work is motivated by the need to enhance the transport in gel-based biosensor devices whose response dynamics are often mass transfer limited. In this case, polyacrylamide gel slabs were doped with immobilized, charged silica colloids, and the flux of a fluorescent tracer was measured as a function of applied field strength, the volume fraction and size of the colloidal silica inclusions, and the bulk electrolyte composition. Significant flux enhancements were achieved with applied electric currents on the order of a few mA. Control experiments indicated that the flux enhancement was not due to any distortion of the gel diffusional properties in response to the presence of the inclusions. At a constant inclusion volume fraction, the electroosmotic solute flux enhancement was strongest for the smallest particle sizes that provide the highest total surface area, consistent with the electroosmotic mechanism whereby fluid flow is generated along the solid/liquid interface.
Electroosmotic convection pumped by charged silica nanoparticle inclusions is demonstrated as a means to enhance mass transport through crosslinked polyacrylamide gels.Figure optionsDownload as PowerPoint slide
Journal: Journal of Colloid and Interface Science - Volume 300, Issue 1, 1 August 2006, Pages 429–436