How metal (hydr)oxides are protonated in aqueous media: The (n+1n+1) rule and the role of the interfacial potential

The mechanism of the protonation of solid metal (hydr)oxides in aqueous media, which is closely interrelated to many processes of great technological and environmental importance, has been elucidated using simulation and experimental work. The electrical potential, smeared out at the interfacial region, changes the concentration of the H+ ions on the surface of the (hydr)oxide, thus promoting or hindering protonation. This is manifested by the shifts of the protonation peaks of the various kinds of surface sites and the appearance of an extra peak in the differential potentiometric titration curve.

Differential potentiometric titration curves of a model oxide with two surface sites ((A) and (C)). Protonation of site A is split into two parts: under negative potential (A) and under positive potential (A′).Figure optionsDownload as PowerPoint slide