کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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61401 | 47581 | 2013 | 10 صفحه PDF | دانلود رایگان |
Monobutyl itaconate (MBI) are commercially prepared by using freshly distilled acetyl chloride as catalysts, which, however, always results in complicated purification processes due to the usage of water-carrying agents. Here, we report the highly selective production of MBI by using zeolite-based hierarchical porous materials as catalysts in the esterification between itaconic acid and n-butyl alcohol. Two typical hierarchically porous-structured catalysts, namely hierarchical mesoporous zeolites (HMZ) and hierarchical nanozeolite assembly (HNZ), with distinctive meso- or nano-porosities and highly crystallized ZSM-5 framework, were prepared, and both of them exhibited high catalytic activity and reusability in the selective esterification between itaconic acid and n-butyl alcohol. The extraordinarily high selectivity to MBI was achieved and attributed to the decreased diffusion restriction in the meso- or nano-porous network and shortened diffusion path in the zeolite framework or zeolites nanocrystals of HMZ and HNZ, respectively, which prevented further esterification of monoesters into diesters.
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► Hierarchical mesoporous zeolites (HMZ) and nanozeolite assembly (HNZ) were prepared.
► HMZ were synthesized by using CTAB and F127 as co-mesoporogens.
► HNZ were prepared in a self-assembly process without secondary porogens.
► Both of them could selectively esterify the nonconjugated carboxyl groups.
► The mesoporosity and shortened diffusion path were found to be the main reasons.
Journal: Journal of Catalysis - Volume 299, March 2013, Pages 20–29