FT-IR study of the reaction mechanisms for photocatalytic reduction of NO with CO promoted by various single-site photocatalysts

Photocatalytic reduction of NO with CO has been carried out using various single-site photocatalysts under UV-light irradiation. The single-site photocatalysts prepared by incorporating transition metal oxides within SiO2 (M/SiO2: MMo, V, and Cr) display different photocatalytic activities. Mo/SiO2 promotes photocatalytic reduction of NO with CO efficiently to produce N2 via the intermediate N2O. V/SiO2 was observed to promote the reaction that leads to selective production of N2O that does not undergo subsequent reduction to form N2. When Cr/SiO2 is used as the photocatalyst, reduction of NO does not take place. The results of Fourier transform infrared investigations reveal that differences in photocatalytic activities are due to different reactivity of reactants-adsorbed transition metal oxides in M/SiO2 and, consequently, the reaction mechanisms for the photocatalytic reduction of NO with CO over M/SiO2 are proposed.

The photocatalytic reduction of NO with CO over Mo/SiO2 proceeds efficiently to produce N2 via N2O as an intermediate product. V/SiO2 promotes the NO reduction reaction, leading to the selective production of N2O without accompanying any further reduction of N2O into N2. When Cr/SiO2 is used as a photocatalyst, reduction of NO does not take place.Figure optionsDownload high-quality image (48 K)Download as PowerPoint slideHighlights
► Various single-site photocatalysts were prepared by a facile impregnation method.
► The local structures of various single-site photocatalysts were investigated.
► Photocatalytic reduction of NO with CO was investigated under UV-light irradiation.
► The reaction mechanisms are described on the basis of FT-IR studies.