کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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61746 | 47603 | 2011 | 12 صفحه PDF | دانلود رایگان |
Novel P-containing oxynitrides VZrPON were tested besides their VZrPO oxide precursors in the ammoxidation of 3-picoline and compared with P-free VZrON catalysts for analysing the influence of both incorporated P and N on the catalytic performance. Results of XRD, XPS, 31P and 51V MAS NMR as well as of simultaneous in situ-EPR/UV–vis/Raman studies during nitridation have shown that the incorporation of phosphorus enhances the V dispersion, reduces vanadium partially even down to V3+ and leads to the formation of a crystalline ZrV2−xPxO7 phase for Zr/V ⩾ 0.5 with V sites surrounded by four O atoms only. N is preferentially incorporated in the vicinity of P, thus, suppressing the formation of VN moieties. These facts may be a reason why the incorporation of P does not markedly improve the catalytic performance of VZrPON catalysts.
The catalytic performance of VZrON and novel P-containing VZrPON oxynitrides is compared in the ammoxidation of 3-picoline. Due to higher VOx dispersion, lower V valence state and a pronounced formation of PN instead of VN bonds VZrPON catalysts are less active but slightly more selective.Figure optionsDownload high-quality image (78 K)Download as PowerPoint slideResearch highlights
► P incorporation raises V dispersion, forms PN and suppresses VN moieties.
► P lowers activity and improves selectivity only slightly.
► 3-CP selectivity rises with rising N surface concentration.
► Impact of N surface sites on selectivity dominates over surface acidity.
Journal: Journal of Catalysis - Volume 277, Issue 2, 24 January 2011, Pages 196–207