کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
62158 | 47624 | 2010 | 8 صفحه PDF | دانلود رایگان |
Supported (PW12O403-) is a suitable counterion to immobilize chiral azabis(oxazoline)–copper complexes through electrostatic interactions (ion pair formation). Catalytic results are good to excellent in cyclopropanation reactions (up to 97% ee). Partial leaching during recycling when mono-exchanged species are present, favored by strong coordination of by-products, can be minimized by a proper solvent choice and by optimization of the recycling system, allowing the recovery and reuse of the catalyst at least six times without loss of activity and enantioselectivities in the range of 82–96% ee for trans-cyclopropanes.
Supported (PW12O403-) is a suitable counterion to immobilize chiral azabis(oxazoline)-copper complexes by ion pair formation. Catalytic results are good to excellent in cyclopropanation reactions (up to 97% ee), with minimized leaching and good recovery after optimization of the recycling system.Figure optionsDownload high-quality image (101 K)Download as PowerPoint slide
Journal: Journal of Catalysis - Volume 275, Issue 1, 30 September 2010, Pages 70–77