کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
62396 47638 2007 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Activation and reactivity of epoxides on solid acid catalysts
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Activation and reactivity of epoxides on solid acid catalysts
چکیده انگلیسی

The aminolysis of epoxides over novel solid catalysts (Brönsted-acidic SBA-15 functionalized with propylsulfonic acid and Lewis-acidic Ti-MCM-41) is reported. The acidic properties of these catalysts were determined by FTIR spectroscopy and temperature-programmed desorption of pyridine and NH3, respectively. The mesoporous solid acids of the present study are reusable and exhibit significantly higher catalytic activities than known catalysts for opening of the oxirane ring with nitrogen (aromatic and aliphatic amines)-containing and oxygen (alcohols)-containing nucleophiles. A range of β-amino alcohols with high regioselectivity and stereoselectivity were synthesized. Adsorption studies as well as the sigmoid shape of the conversion-versus-time plots show that the epoxide and amine compete for adsorption on the acidic sites (SO3H or Ti4+) on the catalyst surface. Epoxide adsorption and activation on acid sites are the more critical processes. Catalytic activity decreases with increasing basicity of the amines and/or the alcohol, as well as the dielectric constant of the solvent.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 252, Issue 2, 10 December 2007, Pages 148–160
نویسندگان
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