کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
63192 | 47675 | 2007 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: High activity of Mn-MgAl hydrotalcite in heterogeneously catalyzed liquid-phase selective oxidation of alkylaromatics to benzylic ketones with 1 atm of molecular oxygen High activity of Mn-MgAl hydrotalcite in heterogeneously catalyzed liquid-phase selective oxidation of alkylaromatics to benzylic ketones with 1 atm of molecular oxygen](/preview/png/63192.png)
Mn-MgAl hydrotalcite, surface-enriched with Mn, was prepared by thermal decomposition of MgAl hydrotalcite followed by reconstruction of its structure in the presence of Mn(II) cations and atmospheric CO2 as a guest inorganic anion through contacting the decomposed mass with aqueous Mn(II) nitrate solution. The Mn-MgAl hydrotalcite showed very high catalytic activity, stability, and reusability in the liquid-phase selective oxidation of a wide range of alkylaromatics to their corresponding benzylic ketones, using atmospheric pressure of molecular O2 as a sole oxidant under solvent-free and mild reaction conditions. The catalytic performance of Mn-MgAl hydrotalcite was found to be much higher than that of Mn-containing hydrotalcites prepared by different methods or MgAl hydrotalcite catalysts containing various other transition metals and synthesized through similar procedures.
Journal: Journal of Catalysis - Volume 247, Issue 2, 25 April 2007, Pages 214–222