|کد مقاله||کد نشریه||سال انتشار||مقاله انگلیسی||ترجمه فارسی||نسخه تمام متن|
|63631||48245||2016||10 صفحه PDF||سفارش دهید||دانلود رایگان|
• Electrolyzed Ni supported on MSN (NiM) was studied for CO2 reforming of CH4.
• Ni was loaded by in-situ (IS), impregnation (IM) and physical mixing (PM) methods.
• NiM_IS exhibited the smallest Ni particles and highest metallic surface area.
• Formation of Ni2O3 and desilication increased the number of basic and defect sites.
• NiM_IS showed the highest catalytic performance and lowest carbon deposition.
A series of Ni/mesostructured silica nanoparticles (NiM) catalysts from an electrolyzed Ni precursor were prepared by in-situ (NiM_IS), impregnation (NiM_IM), and physical mixing (NiM_PM) methods for CO2 reforming of CH4. N2 physisorption indicated that all preparation methods decreased the surface area and pore volume of the mesostructured silica nanoparticles (MSN) which may be attributed to the blockage of the pores by the deposition of NiO particles onto the MSN support. The XRD and H2-TPR analyses indicated that the in-situ method dispersed smaller Ni0 crystallites and exhibited a stronger metal-support interaction compared to the other methods. IR results indicated that the presence of an alkaline electrolyte during the introduction of Ni promoted sequential desilication-substitution of MSN, forming Si–O–Ni. CO2 adsorbed IR and ESR spectroscopies showed that NiM_IS possessed a higher basicity and more defect structures compared to NiM_IM and NiM_PM, owing to the abundant silanol groups and the formation of metal-deficient Ni2O3. At 800 °C, the CH4 and CO2 conversions occur in the order of NiM_IM (CH4 = 45.6 %, CO2 = 52.4%) Figure optionsDownload as PowerPoint slide
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Journal: Journal of CO2 Utilization - Volume 13, March 2016, Pages 71–80