کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
640100 1456957 2016 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of anti-solvents on lignin fractionation of eucalyptus globulus via green solvent system pretreatment
ترجمه فارسی عنوان
تأثیر ضد حلالها بر فرایند لیگنین کربن اکالیپتوس از طریق سیستم پیشگیری از سیستم حلال سبز
کلمات کلیدی
لیگنین، تقسیم بندی، ضد حلال، سیستم حلال سبز
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
چکیده انگلیسی


• Selective dissolution of lignin via ionic liquid–ethanol–water mixture.
• Low-boiling point anti-solvents employed for lignin precipitation.
• High-purity and low-molecular weight lignins get fractionated.

This study focused on the anti-solvents precipitation process of lignin fractionation. Eucalyptus globulus wood was pretreated by ionic liquid–ethanol–water mixture before anti-solvents precipitation experiments. The influence of potential anti-solvents on lignin fractionation was extensively studied. Water, methanol, dichloromethane and iso-propanol were proven effective for lignin fractionation by the formation of precipitation. Lignin fractionation performance (yield and purity) was significantly affected by temperature and anti-solvents dosage. The purity of fractionated lignins increased with growing anti-solvents dosage and temperature. While the yield of fractionated lignins decreased as temperature rose. An increase in anti-solvents dosage could dramatically improve lignin yield. Lignin yield increased to a maximum value, but decreased when the anti-solvents dosage increased further. For different anti-solvents, the sequence on lignin yield was: iso-propanol > water > dichloromethane > methanol. While the sequence of anti-solvents on lignin purity displayed in reverse with lignin yield. Lignins fractionated by different anti-solvents were characterized by FT-IR and GPC. Results showed that the fractionated lignins were G–S type, of low molecular weight, with narrow distribution range (450–2250 g/mol) and extremely low polydispersity (Mw/Mn) value (1.12–1.13). These fractionated lignins could be promising materials for the production of high value chemical and fuels.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 163, 11 May 2016, Pages 258–266
نویسندگان
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