کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
642390 1457034 2012 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Modeling and parameter estimation for a fixed-bed adsorption process for CO2 capture using zeolite 13X
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Modeling and parameter estimation for a fixed-bed adsorption process for CO2 capture using zeolite 13X
چکیده انگلیسی

Modeling of a fixed-bed adsorption process for CO2 capture using zeolite 13X was performed through parameter estimation. An empirical mass transfer rate model is proposed as a relevant description of the adsorption dynamics of CO2/N2 on zeolite 13X. An efficient objective function for the estimation of the mass transfer rate parameters was devised to avoid the local minimum and to improve the convergence to the desired solution. Langmuir isotherm equation coefficients, bed porosity, average particle size, and heat transfer coefficients were determined in separately designed experiments. The porosity estimate was updated during the estimation of mass transfer rate parameters to account for the effect of pore diffusion on bulk flow. To ensure numerically stable computation, the gradient-directed adaptive predictive collocation method was adopted with a cubic spline interpolation function and far-side boundary conditions. The model was experimentally evaluated in an adsorption bed with a height of 70 cm and an inner diameter of 2.54 cm and shown to predict the dynamic behaviors of the process variables with high accuracy.


► Accurate numerical model for an adsorption process for CO2 capture using zeolite 13X.
► A new mass transfer rate model and associated parameter estimation techniques.
► Numerical technique to efficiently integrate stiff PDEs.
► The proposed model was validated through experiments.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 85, 2 February 2012, Pages 120–129
نویسندگان
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