کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
642738 884335 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Stirred cell ultrafiltration of aqueous micellar TX-100 solutions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Stirred cell ultrafiltration of aqueous micellar TX-100 solutions
چکیده انگلیسی

Cellulose membranes with different molecular weight cut-offs (MWCO, 5–100 kDa) were used for the filtration of aqueous micellar TX-100 solutions. The experiments were performed in a stirred cell and surfactant concentration and pressure were varied. The gel-polarization model was employed and showed a gel concentration for TX-100 in the range of 150–300 g/L. Ultrafiltration was also carried out with dimethyl itaconate (DMI) and diethyl itaconate (DEI) as dissolved organic compounds and we found that the solute retention was directly associated to the hydrophobicity of the compounds. The flux was not affected as long as the solution appears homogeneous and the formation of a second phase with higher organic content was avoided. In order to use micellar enhanced ultrafiltration (MEUF) for the recovery of hydrophobic catalysts dissolved in aqueous micellar reaction media, a low MWCO membrane, low surfactant concentrations and hydrophilic reactants should be preferred.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 74, Issue 1, 30 July 2010, Pages 21–27
نویسندگان
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