کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
643469 884374 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Reactive extraction of aldehydes from aqueous solutions with Primene® JM-T
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Reactive extraction of aldehydes from aqueous solutions with Primene® JM-T
چکیده انگلیسی

The reactive extraction of aldehydes from aqueous solutions with primary amine Primene JM-T was explored. The extraction capability of Primene JM-T towards several aldehydes with different molecular structure, ranging from straight chain or branched, saturated or unsaturated aliphatic to aromatic and heterocyclic is investigated. The influences of the process parameters such as initial concentration of both amine and aldehydes as well as the effect of temperature on the extraction equilibrium are investigated. In addition, a simple model incorporating both physical and chemical equilibrium is developed to describe the experimentally observed behaviour. It is noticed that higher initial concentration of the amine results in a higher overall distribution ratio, while for a higher initial concentration of aldehyde, the distribution ratio is lower. The overall extraction performance of the Primene JM-T depends highly on the molecular structure of the aldehyde. It decreases in the following order: pentanal > 3-methylbutanal > benzaldehyde > furfural > 2-methyl-2-butenal. It is observed that the temperature effect on the distribution coefficient is highly dependent on the system studied.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 66, Issue 3, 7 May 2009, Pages 525–531
نویسندگان
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