کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
643518 884376 2008 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Development of process flow sheet for recovery of high pure cobalt from sulfate leach liquor of LIB industry waste: A mathematical model correlation to predict optimum operational conditions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Development of process flow sheet for recovery of high pure cobalt from sulfate leach liquor of LIB industry waste: A mathematical model correlation to predict optimum operational conditions
چکیده انگلیسی

The paper contains a new hydrometallurgical process flow sheet for the recovery of high pure cobalt sulfate solution/salt from waste LiCoO2 cathodic active material generated from lithium ion battery (LIB) industry waste. Cobalt was recovered as cobalt sulfate from sulfate leach liquor by solvent extraction process using Cyanex 272 as an extractant. For quantitative extraction of pure cobalt from waste LiCoO2 different process parameters such as concentration of Cyanex 272, O/A volume ratio, McCabe–Thiele extraction isotherm, scrubbing isotherm required were optimized. A mathematical model was developed to correlate metal extractability and Cyanex 272 concentrations and volume content. Optimum conditions required for quantitative extraction of pure cobalt sulfate/salt using Cyanex 272 were estimated by a proposed model. From predicted model, the mechanism for extraction and McCabe–Thiele isotherm for extraction were derived and compared with obtained results. A good agreement between proposed model and observed results was indicated. The cobalt loaded Cyanex 272 was stripped with sulfuric acid and 99.99% pure cobalt sulfate was obtained.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 63, Issue 2, 22 October 2008, Pages 360–369
نویسندگان
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