کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
643884 | 884395 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Removal enrichment and recovery of Ni(II), Zn(II) and phosphate from phosphation rinsing waters with liquid-phase polymer-based retention technique
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
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چکیده انگلیسی
The removal enrichment and recovery of Ni(II), Zn(II) and phosphate with liquid-phase polymer-based retention (LPR) was studied on a laboratory level and on a pilot scale with real wastewater. Hyperbranched poly(ethylenimine) (HBPEI) was used, in favour, as complexing and ion exchange agent. Sorption behaviour and loading capacities of the polymer with respect to Ni(II), Zn(II), Mn(II) and phosphate were studied under various conditions in order to implement the system into a pilot unit for the treatment of industrial phosphation rinsing waters. The recovery of Ni(II) and Zn(II), accomplished in that pilot unit, constantly reached values over 99%. Starting from an initial metal concentration of around 20 mg lâ1 enrichment up to 1000 mg lâ1 for Ni(II) and Zn(II) was achieved. At the same time the heavy metal concentration of the discharge water always remained below the German discharge limits of 0.5 mg lâ1 Ni(II) and 2 mg lâ1 Zn(II), respectively. Phosphate anions were also enriched and partially recovered.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 63, Issue 1, 1 October 2008, Pages 172-178
Journal: Separation and Purification Technology - Volume 63, Issue 1, 1 October 2008, Pages 172-178
نویسندگان
Michael Schulte-Bockholt, Michael Schuster,