کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
644357 884439 2006 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Transport model for solvent permeation through nanofiltration membranes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Transport model for solvent permeation through nanofiltration membranes
چکیده انگلیسی

This paper describes a new, semi-empirical model for solvent transport through nanofiltration membranes. The model is based on different existing models: Hagen–Poiseuille, Jonsson and Boesen, Machado et al. and Bhanushali et al. The newly developed model introduces a correction to the Bhanushali model. Solvent flux appears to be dependent on viscosity, molecular size and the difference in surface tension between the membrane and the solvent. The model was tested on the results of a series of permeability experiments of binary mixtures of water, methanol and/or ethanol, carried out with seven (hydrophilic and hydrophobic) membranes: Desal-5-DK, Desal-5-DL, N30F, NF-PES-010, MPF-44, MPF-50 and SolSep-030505. The model fits indicated a high correlation with experimental results. The new model showed similar fitting results as existing models for hydrophilic membranes. The solvents used have a relatively high degree of affinity for hydrophilic surfaces, resulting in small repulsion forces and consequently a reduced influence of the membrane–solvent interactions. Thus, existing models are sufficient for hydrophilic membranes and the correction for membrane–solvent interactions proposed here has only a small influence. However, a significant improvement was found for the description of the solvent permeability through hydrophobic membranes. For hydrophobic membranes, the relative importance of membrane–solvent interactions/repulsions is increasing for polar solvents. Existing models could not describe the steep increase in permeability for mixtures with high alcohol fractions, whereas the new model fits significantly better.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 48, Issue 3, 15 March 2006, Pages 255–263
نویسندگان
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