کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6455575 1419756 2017 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Mechanism of ethylene oxychlorination over ruthenium oxide
ترجمه فارسی عنوان
مکانیسم اکسایکلرینگ اتیلن بر روی اکسید روتونیوم
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی


- The mechanism of ethylene oxychlorination on RuO2 is investigated by DFT calculations.
- Chlorination is governed kinetically whereas oxidation is controlled thermodynamically.
- The degree of surface chlorination is a key factor determining the selectivity.
- Coadsorbed Cl destabilises intermediates and thus favours EDC over VCM formation.
- A set of requirements for a good VCM production catalyst is provided.

The oxychlorination of ethylene is an industrially relevant process within the manufacture of polyvinyl chloride (PVC). Although RuO2 is the best performing catalyst for the Deacon process (4HCl + O2 → 2H2O + 2Cl2), experiments demonstrate a modest activity in the selective oxychlorination to vinyl chloride, favouring oxidation and polychlorinated saturated products. From the computational modelling three main contributions are found to control the performance: (i) coverage effects that alter the configuration of intermediates; (ii) the monodimensional arrangement of the active sites, in which the reaction of coadsorbed species works on a “first-come, first-served” basis; and (iii) the high reactivity of the oxygen species. Competition between oxidation and chlorination processes results in variable selectivity, depending on the reaction conditions (particularly temperature and reactant partial pressures), which influence the surface composition. From the analysis of the complex reaction network, the essential requirements for a good oxychlorination catalyst are formulated.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 353, September 2017, Pages 171-180
نویسندگان
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