کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6455946 | 1419766 | 2016 | 6 صفحه PDF | دانلود رایگان |
- The conversion of carbon dioxide to chemicals with hydrosilanes.
- Recyclable solid poly-N-heterocyclic carbene catalyzed CO2 reduction.
- Heterogeneous organocatalyst catalyzed conversion of CO2 to methanol and formamides.
The utility of solid poly-N-heterocyclic carbene (poly-NHC) materials as organocatalysts for carbon dioxide reduction was studied. These poly-NHC particles were demonstrated to be useful as heterogeneous organocatalysts for the reduction of carbon dioxide to methanol and for the formylation of N-H bonds with hydrosilanes as a hydride donor. These solid catalysts could potentially be useful in large-scale syntheses due to the ease of catalyst recycle and reuse, providing cost savings and environmental sustainability in the long run.
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Journal: Journal of Catalysis - Volume 343, November 2016, Pages 46-51