Experimental and modeling study of adsorption and diffusion of gases in Cu-BTC

▸ Screening of Cu-BTC synthesis recipe based on stable CO2 capacity after several regenerations. ▸ Equilibrium isotherms of CO2, CH4 and N2 on in-house and commercial Cu-BTC samples. ▸ Breakthrough measurements, modeling and analysis for identification of transport mechanism. ▸ Experimental validation of a reliable method for extra-column dead volume correction.