کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6594585 458443 2010 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
1,3-phosphorus zwitterions with cyano-group at anion center
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
1,3-phosphorus zwitterions with cyano-group at anion center
چکیده انگلیسی
This review focuses on synthesis and properties of 1,3-phosphorus-containing zwitterions that have at the anionic center cyano-group and either ester (type one) or carbamate (type two) moieties. Zwitterions belonging to type one possess dual nucleophile reactivity, i.e., depending on the properties of the electrophiles they may form either C- or N-derivatives. Zwitterions belonging to type two possess triple nucleophile reactivity. In their reactions with electrophiles, they may form even three types of derivatives, i.e., at the C-, O- or N-atoms. This nucleophile multiplicity is not just interesting from the theoretical standpoint but may also open the ways to the synthesis of new compounds that can be important from the practical standpoint, such as physiologically active compounds, catalysts, analytical reagents, etc.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Comptes Rendus Chimie - Volume 13, Issues 8–9, August–September 2010, Pages 900-911
نویسندگان
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