کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6597982 1423877 2018 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Novel pyrazolone derivatives and corresponding europium(III) complexes: Synthesis and properties research
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Novel pyrazolone derivatives and corresponding europium(III) complexes: Synthesis and properties research
چکیده انگلیسی
A series of pyrazolone derivatives ligands L1−7 were successfully synthesized and validated by 1H NMR and MS, corresponding europium complexes [EuL1−7(NO3)2]NO3·EtOAc were synthesized. Physico-chemistry properties of title complexes were determined by Elemental analysis, Molar conductance, UV absorption spectra, IR spectra and Thermogravimetric analysis. The title complexes exhibit characteristic red fluorescence of Eu3+. The effect of various substituent groups in ligands on the of title Eu3+ complexes is ordered: Cl > -Br > -OCH3 > -F > -CH3 > -H > -NO2, and [EuL6(NO3)2]NO3·EtOAc containing Cl possesses the strongest fluorescence intensity, so does fluorescence quantum yield. The electrochemical properties indicate that energy gap Eg and LUMO energy level are huge affected by substituent groups, and variation trends of LUMO energy level affected by diverse substituent groups are also different. The prepared title europium complexes have potential application prospects in the fields of photoelectric functional materials and life sciences.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 158, November 2018, Pages 28-35
نویسندگان
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